TcSUH
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Bi-Weekly Seminar
Strain and n-Type Doping Effects on Colossal Magnetoresistance Films
by: Prof. Hsiung Chou
Date: Friday August 18, 2006
Time: 12:00 pm – 1:00 pm
Location: Houston Science Center – Building 593 — Room 102
Overview
The mechanism of strain effect and the achievement of n-type doping on colossal magnetoresistance (CMR) films has been debated and tried for the past decade. It has been believed, but there has been a lack of direct evidence to support, that the distorted MnO6 octahedron due to in-plane strain effect causes the change of transport and magnetic properties. To investigate the origin of the strain effect, La0.7Ca0.3MnO3 and La0.8Ba0.2MnO3 films with various thicknesses grown on SrTiO3 substrates were examined by Near Edge X-ray Absorption Spectroscopy (NEXAS). This study finds that the strain doesn’t affect the MnO6 octahedron significantly, but weakens substantially the La-O and Ca-O (or Ba-O) hybridization, which is responsible for the reduction and the enhancement of TC in La0.7Ca0.3MnO3 and La0.8Ba0.2MnO3 strain films, respectively. For the n-type CMR issue, it has been believed that an n-type CMR can be realized by partially substituting tetravalent ions on trivalent La3+ sites. By investigating the La0.7(Ce or Te)0.3MnO3 bulks with SEM and EDS, it is found that the compound decomposed into La0.9-&epsilonCe&epsilonMnO3+&epsilon, Mn-O, and CeO2, none of which contained original stochiomatry. The n-type compound cannot be formed in thermal equilibrium process, such as post annealing. Only those under metastable processing such as in-situ epitaxial films can possibly assist in forming n-type CMR.
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Bi-Weekly Seminar
Neutron Reflectivity from NbTi/Nb Multilayers
by: Dr. Wolfgang Donner
Date: Friday August 04, 2006
Time: 12:00 pm – 1:00 pm
Location: Houston Science Center – Building 593 — Room 102
Overview
Thin film multilayers of superconducting materials display unusually high pinning forces compared to their bulk counterparts. One such system is NbTi/Nb multilayers: here it was found that the critical current density of such multilayers sensitively depends on the multilayer periodicity. It has been speculated that the vortex lattice in those multilayers would “match†the multilayer period under an applied external field of sufficient magnitude.
The talk presents results on the growth, x-ray and neutron characterization of NbTi/Nb multilayers in an effort to test the hypothesis of vortex lattice “matching.”
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Bi-Weekly Seminar
Does DNA act as it's own sunscreen?
by: Prof. Eric Bittner
Date: Friday July 07, 2006
Time: 12:00 pm – 1:00 pm
Location: Houston Science Center – Building 593 — Room 102
Overview
DNA is a surprisingly robust molecular system in spite of its rather large UV absorption cross-section in the 310-290 nm range. Part of this robustness comes from DNA's ability to rapidly dissipate the electronic photoexcitation energy into heat, thus preventing to some extent photochemical processes that can lead to mutation. One of the key questions is whether or not this dissipation is due to base-pairing and hydrogen transfer in localized excited states or if it is due to base-stacking effects. In this talk, I shall give an overview of our two-band lattice model for the excited states of DNA double helices. Our theoretical calculations corroborates recent ultrafast experimental results that indicate that base-stacking dictates the fate of an excitation in A-T DNA. Moreover, our work suggest that in AT DNA, excitonic dynamics along the A chain is dramatically different than along the T chain. Finally, we speculate that these processes may have played a crucial role in the evolutionary selection of DNA.
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Bi-Weekly Seminar
Interface - A Key Role to Functional Thin Film Epitaxy
Date: Friday March 03, 2006
Time: 12:00 pm – 1:00 pm
Location: Houston Science Center – Building 593 — Room 102
Overview
Driven in parallel by technological needs and basic sciences and engineering's inquisitiveness, there has been an explosion in the development of new materials over the last decades, especially in the nanoscale regime. Interface, an unforgettable topic, has attracted more and more attention in the functional materials research and active device fabrication. It plays a key role in controlling the physical properties of advanced materials and result in the discovery of various new phenomena with an excellent opportunity for developing new materials for active nanostructures and their engineered nanosystems. We have focused on the systematic investigation of interface effects on highly epitaxial functional oxide thin films and have achieved many excellent results. For instance, we have achieved an extremely high dielectric tenability of 80% from highly epitaxial ferroelectric Mn:(Ba,Sr)TiO3 thin films, strong anisotropic phenomena in highly epitaxial (Pb,Sr)TiO3, a new record of giant magnetoresistance ratio of 1010 from artificial domain structural epitaxial (La,Ca)MnO3 thin films, the interface-controlled oxide nanorod/ribbon highly epitaxial thin films, and many other results. A series of models were developed to understand these interface phenomena. Details will be presented in the talk.
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Bi-Weekly Seminar
Novel Bioelectric Phenomena in Cellular Organelles
Date: Friday February 03, 2006
Time: 12:00 pm – 1:00 pm
Location: Houston Science Center – Building 593 — Room 102
Overview
We have been investigating unusual bioelectric phenomena using novel, generally noninvasive, sensors. Recent topics of interest include: (1) studies of harmonic response of active membrane pumps (P-type ATPases), which we have observed in budding yeast cells using superconducting quantum interference devices (SQUIDs); (2) nonlinear harmonics, in response to sinusoidal electric fields, produced by electron transport chain complexes and a molecular turbine, known as ATP synthase, in mitochondria; (3) similar studies of light-activated harmonics, which we have recently discovered in chloroplasts; and (4) studies of the dielectric and conducting properties of cytoskeletal proteins, such as tubulin heterodimers, which self-assemble to form microtubules.
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